Environmentally Friendly, Photochemical Access to []Au III Pincer Complexes By Oxidative Addition
نویسندگان
چکیده
منابع مشابه
Green primaries: environmentally friendly energetic complexes.
Primary explosives are used in small quantities to generate a detonation wave when subjected to a flame, heat, impact, electric spark, or friction. Detonation of the primary explosive initiates the secondary booster or main-charge explosive or propellant. Long-term use of lead azide and lead styphnate as primary explosives has resulted in lead contamination at artillery and firing ranges and be...
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CsBr3 was investigated as a new and convenient oxidant for NHC-Au(I) complexes (NHC = imidazo[1,5-a]pyridin-3-ylidene) for the preparation of the respective Au(III) complexes. The Au(I) complexes were synthesized by the silver salt method using [(NHC)2Ag]PF6 and (tht)AuBr. Unexpectedly, the reactions yielded both neutral (NHC)AuBr and ionic [(NHC)2Au]PF6, depending on the N-substituent of the N...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2021
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.202100035